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2008 Standards & Guidelines for Contaminants in Massachusetts Drinking Water

The Drinking Water List of Standards and Guidelines is a convenient compendium of guidance values available for evaluating contaminants in drinking water in Massachusetts. The list is designed to be used by individuals or groups concerned with the integrity of drinking water, for example, water suppliers, homeowners, environmental groups, government regulators, boards of health, or private consultants.

In addition to the drinking water standards and guidelines listed below, MassDEP has also derived Immediate Action Levels for routinely used water treatment chemicals, to enable water treatment plant operators to identify and address serious incidents of chemical overfeed or misuse. These may be found at: http://mass.gov/dep/water/laws/ialwtps.htm.

The guidance values are contained in five separate lists, in the following order:


There have been no changes to these values from last year's lists. 

Inorganic and Organic Chemicals
Substance
CASRN
MMCL (mg/L)
Acrylamide [1]
79061
Treatment Technique
Alachlor
15972608
0.002
Antimony
7440360
0.006
Arsenic
7440382
0.010
Asbestos [2]
1332214
7 million fibers/liter
Atrazine
1912249
0.003
Barium
7440393
2
Benzene
71432
0.005
Benzo(a)pyrene
50328
0.0002
Beryllium
7440417
0.004
Bromate
15541454
0.010
Cadmium
7440439
0.005
Carbofuran
1563662
0.04
Carbon tetrachloride
56235
0.005
Chloramines (as Cl2)
N/A
4.0 (MRDL [3])
Chlordane
57749
0.002
Chlorine (as Cl2)
7782505
4.0 (MRDL)
Chlorine dioxide (as ClO2)
10049044
0.8 (MRDL)
Chlorite
7758192
1.0
Chlorobenzene
108907
0.1
Chromium (total)
7440473
0.1
Copper
7440508
Treatment Technique, 1.3 (Action Level)
Cyanide (as free cyanide)
57125
0.2
2,4-D (2,4-Dichlorophenoxyacetic acid)
94757
0.07
Dalapon
75990
0.2
1,2-Dibromo-3-chloropropane (DBCP)
96128
0.0002
1,2-Dichlorobenzene (o-DCB)
95501
0.6
1,4-Dichlorobenzene (p-DCB) [4]
106467
0.005
1,2-Dichloroethane
107062
0.005
1,1-Dichloroethylene
75354
0.007
1,2-Dichloroethylene(cis)
156592
0.07
1,2-Dichloroethylene(trans)
156605
0.1
Dichloromethane
75092
0.005
1,2-Dichloropropane
78875
0.005
Di(2-ethylhexyl)-adipate
103231
0.4
Di(2-ethylhexyl)-phthalate
117817
0.006
Dinoseb
88857
0.007
Diquat
85007
0.02
Endothall
145733
0.1
Endrin
72208
0.002
Epichlorohydrin [5]
106898
Treatment Technique
Ethylbenzene
100414
0.7
Ethylene dibromide (EDB) [6]
106934
0.00002
Fluoride
7782414
4.0
Glyphosate
1071536
0.7
Haloacetic acids (HAA5) (for chlorinated supplies only): including monochloroacetic acid, dichloroacetic acid, trichloroacetic acid, bromoacetic acid and dibromoacetic acid
N/A
0.060
Heptachlor
76448
0.0004
Heptachlor epoxide
1024573
0.0002
Hexachlorobenzene
118741
0.001
Hexachlorocyclopentadiene
77474
0.05
Lead
7439921
Treatment Technique, 0.015 (Action Level)
Lindane
58899
0.0002
Mercury (inorganic)
7439976
0.002
Methoxychlor
72435
0.04
Nitrate (As N)
14797558
10
Nitrate/Nitrite (total)
N/A
10
Nitrite (As N)
14797650
1
Oxamyl (Vydate)
23135220
0.2
PCBs (Polychlorinated biphenyls) [7]
1336363
0.0005
Pentachlorophenol
87865
0.001
Perchlorate [8]
Various
0.002
Picloram
1918021
0.5
Selenium
7782492
0.05
Simazine
122349
0.004
Styrene
100425
0.1
2,3,7,8-TCDD (Dioxin)
1746016
3 x 10-8
Tetrachloroethylene
127184
0.005
Thallium
7440280
0.002
Toluene
108883
1
Total trihalomethanes (for chlorinated supplies only)
N/A
0.080
Including: Chloroform
67663
N/A [9]
  Chlorodibromomethane
124481
N/A
  Bromodichloromethane
75274
N/A
  Bromoform
75252
N/A
Toxaphene
8001352
0.003
2,4,5-TP (Silvex)
93721
0.05
1,2,4-Trichlorobenzene 
120821
0.07
1,1,1-Trichloroethane
71556
0.2
1,1,2-Trichloroethane
79005
0.005
Trichloroethylene
79016
0.005
Vinyl chloride
75014
0.002
Xylenes (total)
1330207
10

[1] No numerical MCL is provided for these compounds. If detected, a treatment technique is specified. Each water system must certify, in writing, to the state (using third-party or manufacturer’s certification) that when acrylamide and epichlorohydrin are used in drinking water systems, the combination (or product) of dose and monomer level does not exceed the levels specified, as follows:

  • Acrylamide = 0.05% dosed at 1 mg/L (or equivalent)
  • Epichlorohydrin = 0.01% dosed at 20 mg/L (or equivalent)

[2]For fibers longer than 10 microns.

[3]MRDL = maximum residual disinfectant level - the highest level of a disinfectant allowed in drinking water. There is convincing evidence that addition of a disinfectant is necessary for control of microbial contaminants.

[4] The MMCL for this chemical is more stringent than the federal MCL.

[5]See footnote 1 above.

[6]See footnote 4 above.

[7] The MCL for PCBs applies to the decachlorobiphenyl species.

[8]The MCL is directed at the sensitive subgroups of pregnant women, infants, children up to the age of 12, and individuals with hypothyroidism. They should not consume drinking water containing concentrations of perchlorate exceeding 2 mg/L. MassDEP recommends that no one consume water containing perchlorate concentrations greater than 18 mg/L.

[9]Not applicable

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Radionuclides
Substance
CASRN
TYPE of GUIDANCE
MMCL or ORSG (mg/L)
Beta particle and photon radioactivity
N/A
MMCL
concentration which produces an annual dose of 4 millirem/yr
Gross alpha radiation
N/A
MMCL
15 pCi/l
Radium (226 + 228)
7440144
MMCL
5 pCi/l
Radon-222 [10]
14859677
ORSG
10,000 pCi/l
Uranium
7440611
MMCL
0.030

[10] Exceedance of this guideline indicates that air sampling for Radon-222 should be done. EPA proposed guidelines for radon (64 FR 211; Tuesday, November 2, 1999) which have not been finalized.

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Biologicals
Substance
CASRN
MMCL
Cryptosporidium
N/A
Treatment Technique
Giardia lamblia
N/A
Treatment Technique
Heterotrophic plate count
N/A
Treatment Technique
Legionella
N/A
Treatment Technique
Total coliform bacteria (including fecal coliform and E. coli)
N/A
refer to 310 CMR 22.05
Turbidity
N/A
Treatment Technique
Viruses (enteric)
N/A
Treatment Technique

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Massachusetts Drinking Water Guidelines
Substance
CASRN
ORSG (mg/L)
Acetone
67641
6.3
Aldicarb [11]
116063
0.003
Aldicarb sulfone [12]
1646884
0.002
Aldicarb sulfoxide [13]
1646873
0.004
Bromomethane
74839
0.01
Chloroform [14]
67663
0.07
Dichlorodifluoromethane
75718
1.4
1,1-Dichloroethane
75343
0.07
1,3-Dichloropropene
542756
0.0004
1,4-Dioxane
123911
0.003
Ethylene glycol
107211
14
Methyl ethyl ketone
78933
4.0
Methyl isobutyl ketone
108101
0.35
Methyl tertiary butyl ether [15]
1634044
0.07
Metolachlor
51218452
0.1
Naphthalene
91203
0.140
Nickel [16]
7440020
0.1
n-Nitrosodimethylamine (NDMA)
62759
0.00001
Petroleum hydrocarbons: [17]
TPH
N/A
0.2
Aliphatics:  
C5-C8
0.3
C9-C12 [18]
0.7
C9-C18 [19]
0.7
C19-C36
14.0
Aromatics:  
C6-C8
use guidance for individual chemicals
C9-C10
0.2
C11-C22
0.2
Sodium [20]
7440235
20
Tertiary-Amyl Methyl Ether (TAME)
994058
0.09
Tertiary Butyl Alcohol (TBA)
75650
0.12
Tetrahydrofuran
109999
1.3
1,1,2-Trichloro-1,2,2-trifluoroethane (FREON 113)
76131
210

All guidelines are current with the information listed in the U.S. EPA Integrated Risk Information System (IRIS) as of March 19, 2008, except where noted.

[11] The MCLs for aldicarb, aldicarb sulfone and aldicarb sulfoxide have been stayed.

[12] See footnote 11 above.

[13] See footnote 11 above.

[14] This guideline applies to non-chlorinated water supplies. For chlorinated drinking water supplies, please contact the Drinking Water Program.

[15] The health-based guidelinefor MTBE was reviewed by ORS in 2000.

[16] The MCL for Nickel has been remanded and is no longer in effect; however, the current EPA IRIS chronic oral reference dose for soluble salts of nickel (http://www.epa.gov/iris/subst/0271.htm) supports this value and it is also the currently listed EPA Life-time Health Advisory value (http://www.epa.gov/waterscience/criteria/drinking/dwstandards.pdf).

[17] Monitoring for these compounds is not required but is done on a case-by-case basis. These limits may be used when evaluating health risks posed by clearly identified mixtures of petroleum hydrocarbon compounds. The analytical methods to use to generate data to compare to the Drinking Water Guidelines are the Volatile Petroleum Hydrocarbon (VPH) and the Extractable Petroleum Hydrocarbon (EPH) methods developed by the MassDEP (MassDEP 1998).

[18] The overlap in the C9-C12 range is the result of the VPH and EPH analytical methods used to quantitate these ranges of petroleum hydrocarbons in drinking water. The choice of themost appropriate range to use is based on the identity of the petroleum product of concern and is therefore determined on a case-specific basis.

[19] See footnote 9 above.

[20] All detections of sodium must be reported. Please refer to 310 CMR 22.06A for the specific requirements. The sodium guideline of 20 mg/L is based on an eight (8) ounce serving.

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Secondary Maximum Contaminant Levels
Chemicals/Parameter
Status
SMCL (mg/L)
Aluminum
0.05 to 0.2
Chloride
F
250
Color
F
15 Color Units
Copper
F
1
Corrosivity
F
non-corrosive
Fluoride
F
2
Foaming agents
F
0.5
Iron
F
0.3
Manganese
F
0.05
Methyl tertiary butyl ether [22]
0.020-0.040
Odor
F
3 threshold odor numbers
pH
F
6.5 - 8.5
Silver
F
0.10
Sulfate
F
250 [24]
Total dissolved solids (TDS)
F
500
Zinc
F
5

Secondary Standards are referenced in the Massachusetts Drinking Water Regulations (310 CMR 22.07 (d)).

[21] Final

[22] The secondary MCL for MTBE is based on the Drinking Water Advisory set by EPA and is based on taste and odor considerations.

[23] Advisory

[24] An MCL of 500 mg/L has been proposed by USEPA (Federal Register 12/20/94).

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Contact Information

For more information about these standards please contact Michael Hutcheson, MassDEP Office of Research and Standards, at:
michael.hutcheson@state.ma.us or 617-292-5998.

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