The EPA publication SW-846, entitled Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, is the Office of Solid Waste's (OSW's) official compendium of analytical and sampling methods that have been evaluated and approved for use in complying with the RCRA regulations. SW-846 functions primarily as a guidance document setting forth acceptable, although not required, methods for the regulated and regulatory communities to use in responding to RCRA-related sampling and analysis requirements.
SW-846 is a multi-volume document that changes over time as new information and data are developed. It has been issued by EPA since 1980 and is currently in its third edition. Advances in analytical instrumentation and techniques are continually reviewed by OSW and incorporated into periodic updates to SW-846 to support changes in the regulatory program and to improve method performance and cost effectiveness. To date, EPA has finalized Updates I, II, IIA, IIB, III and IIIA to the SW-846 manual, and the updated and fully integrated manual contains approximately 3500 pages. The Methods Team of OSW has also made Draft Updates IVA and IVB for public use. Note: all files linked from EPA.
SW-846 Method 6010D: INDUCTIVELY COUPLED PLASMA-ATOMIC EMISSION SPECTROMETRY
SW-846 Method 6020B: INDUCTIVELY COUPLED PLASMA-MASS SPECTROMETRY
SW-846 7000 Series Methods: ATOMIC ABSORPTION METHODS
SW-846 Method 7196A: CHROMIUM, HEXAVALENT (COLORIMETRIC)
SW-846 Method 7470/7471: MERCURY IN LIQUID WASTE (MANUAL COLD-VAPOR TECHNIQUE)
SW-846 Method 8021B: AROMATIC AND HALOGENATED VOLATILES BY GAS CHROMATOGRAPHY USING PHOTOIONIZATION AND/OR ELECTROLYTIC CONDUCTIVITY DETECTORS
SW-846 Method 8081B: ORGANOCHLORINE PESTICIDES BY GAS CHROMATOGRAPHY
SW-846 Method 8082: POLYCHLORINATED BIPHENYLS (PCBs) BY GAS CHROMATOGRAPHY
SW-846 Method 8151A: CHLORINATED HERBICIDES BY GC USING METHYLATION OR PENTAFLUOROBENZYLATION DERIVATIZATION
SW-846 Method 8260B: VOLATILE ORGANIC COMPOUNDS BY GAS CHROMATOGRAPHY/MASS SPECTROMETRY (GC/MS)
SW-846 Method 8270D: SEMIVOLATILE ORGANIC COMPOUNDS BY GAS CHROMATOGRAPHY/MASS SPECTROMETRY (GC/MS)
SW-846 Method 8330: NITROAROMATICS AND NITRAMINES BY HIGH PERFORMANCE LIQUID CHROMATOGRAPHY (HPLC)
SW-846 Method 9014: TITRIMETRIC AND MANUAL SPECTROPHOTOMETRIC DETERMINATIVE METHODS FOR CYANIDE